Poly[[{μ4-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(I)] benzene solvate]
نویسنده
چکیده
In the title complex, {[Ag(2)(CF(3)O(3)S)(2)(C(30)H(20)N(6))]·C(6)H(6)}(n), the two independent Ag(I) ions are each coordinated by two N atoms and one O atom in a 'T-shaped' geometry. In the crystal structure, 1,2-bis-[(3-cyano-benzyl-idene)hydrazono]-1,2-diphenyl-ethane ligands act as bridging ligands and each coordinates to four Ag(I) ions, resulting in a one-dimensional chain structure. The crystal structure is stabilized by weak inter-molecular C-H⋯O hydrogen bonds.
منابع مشابه
Poly[[{μ3-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}silver(I)] hexafluoridoantimonate]
In the title compound, {[Ag(C(30)H(20)N(6))][SbF(6)]}(n), the Ag(+) cation has a three-coordinate environment completed by three N atoms of the 1,2-bis-[(3-cyano-benzyl-idene)hydrazono]-1,2-diphenyl-ethane ligand. The Ag(+) cation coordination geometry is best described as distorted T-shaped. The crystal structure forms a three-dimensional structural polymer.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008